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To check LVS using Calibre tool a few following steps are needed.
In new create CDL window (at 1st run) fill a Library name and Top cell name fields with appropriate names. Change run directory if necessary (Calibre LVS generate large number of files)
In CDL processor for LVS window change Run directory to directory with netlist file. Mark the netlist file and move (i.e. using double-click) to files to process tab.